'When you galvanize steel you put
a barrier between the steel surface and the environment. Galvanizing
isn't just zinc coating, it is a metallurgical bond between the two
different types of metal.'
If the galvanized steel
coating is damaged in any way you would expect the metal underneath to
rust, but this is not the case. In fact something all together
different happens, an action called sacrificial protection. This is
where the zinc itself oxidizes to protect the metal underneath. To
understand this process you have to look at the galvanic series of
metals, which shows that zinc is closer to the electronegative end than
both steel and iron. This simply means that zinc is a far more active
metal and is the first one to corrode. It is this corrosion of the zinc
that protects the metal underneath by filling the hole in the coating
with zinc oxides.